Appendix C to Part 438 - Metal-Bearing Operations Definitions
40:32.0.1.1.14.3.4.1.18 : Appendix C
Appendix C to Part 438 - Metal-Bearing Operations Definitions Note:
The definitions in this appendix shall not be used to
differentiate between the six “core” metal finishing operations
(i.e., Electroplating, Electroless Plating, Anodizing,
Coating (chromating, phosphating, and coloring), Chemical Etching
and Milling, and Printed Circuit Board Manufacture) and forty
“ancillary” process operations listed at 40 CFR 433.10(a).
Abrasive Jet Machining includes removing stock material
from a part by a high-speed stream of abrasive particles carried by
a liquid or gas from a nozzle. Abrasive jet machining is used for
deburring, drilling, and cutting thin sections of metal or
composite material. Unlike abrasive blasting, this process operates
at pressures of thousands of pounds per square inch. The liquid
streams typically are alkaline or emulsified oil solutions,
although water also can be used.
Acid Pickling Neutralization involves using a dilute
alkaline solution to raise the pH of acid pickling rinse water that
remains on the part after pickling. The wastewater from this
operation is the acid pickling neutralization rinse water.
Acid Treatment With Chromium is a general term used to
describe any application of an acid solution containing chromium to
a metal surface. Acid cleaning, chemical etching, and pickling are
types of acid treatment. Chromic acid is used occasionally to clean
cast iron, stainless steel, cadmium and aluminum, and bright
dipping of copper and copper alloys. Also, chromic acid solutions
can be used for the final step in acid cleaning phosphate
conversion coating systems. Chemical conversion coatings formulated
with chromic acid are defined at “Chromate Conversion Coating (or
Chromating)” in this appendix. Wastewater generated during acid
treatment includes spent solutions and rinse waters. Spent
solutions typically are batch discharged and treated or disposed of
off site. Most acid treatment operations are followed by a water
rinse to remove residual acid.
Acid Treatment Without Chromium is a general term used to
describe any application of an acid solution not containing
chromium to a metal surface. Acid cleaning, chemical etching, and
pickling are types of acid treatment. Wastewater generated during
acid treatment includes spent solutions and rinse waters. Spent
solutions typically are batch discharged and treated or disposed of
off site. Most acid treatment operations are followed by a water
rinse to remove residual acid.
Alcohol Cleaning involves removing dirt and residue
material from a part using alcohol.
Alkaline Cleaning Neutralization involves using a dilute
acid solution to lower the pH of alkaline cleaning rinse water that
remains on the part after alkaline cleaning. Wastewater from this
operation is the alkaline cleaning neutralization rinse water.
Alkaline Treatment With Cyanide is the cleaning of a
metal surface with an alkaline solution containing cyanide.
Wastewater generated during alkaline treatment includes spent
solutions and rinse waters. Alkaline treatment solutions become
contaminated from the introduction of soils and dissolution of the
base metal. They usually are treated and disposed of on a batch
basis. Alkaline treatment typically is followed by a water rinse
that is discharged to a treatment system.
Anodizing With Chromium involves producing a protective
oxide film on aluminum, magnesium, or other light metal, usually by
passing an electric current through an electrolyte bath in which
the metal is immersed. Anodizing may be followed by a sealant
operation. Chromic acid anodic coatings have a relatively thick
boundary layer and are more protective than are sulfuric acid
coatings. For these reasons, chromic acid is sometimes used when
the part cannot be rinsed completely. These oxide coatings provide
corrosion protection, decorative surfaces, a base for painting and
other coating processes, and special electrical and mechanical
properties. Wastewaters generated during anodizing include spent
anodizing solutions, sealants, and rinse waters. Because of the
anodic nature of the process, anodizing solutions become
contaminated with the base metal being processed. These solutions
eventually reach an intolerable concentration of dissolved metal
and require treatment or disposal. Rinse water following anodizing,
coloring, and sealing typically is discharged to a treatment
system.
Anodizing Without Chromium involves applying a protective
oxide film to aluminum, magnesium, or other light metal, usually by
passing an electric current through an electrolyte bath in which
the metal is immersed. Phosphoric acid, sulfuric acid, and boric
acid are used in anodizing. Anodizing also may include sealant
baths. These oxide coatings provide corrosion protection,
decorative surfaces, a base for painting and other coating
processes, and special electrical and mechanical properties.
Wastewater generated during anodizing includes spent anodizing
solutions, sealants, and rinse waters. Because of the anodic nature
of the process, anodizing solutions become contaminated with the
base metal being processed. These solutions eventually reach an
intolerable concentration of dissolved metal and require treatment
or disposal. Rinse water following anodizing, coloring, and sealing
steps typically is discharged to a treatment systems.
Carbon Black Deposition involves coating the inside of
printed circuit board holes by dipping the circuit board into a
tank that contains carbon black and potassium hydroxide. After
excess solution dips from the circuit boards, they are heated to
allow the carbon black to adhere to the board.
Catalyst Acid Pre-Dip uses rinse water to remove residual
solution from a part after the part is processed in an acid bath.
The wastewater generated in this unit operation is the rinse
water.
Chemical Conversion Coating without Chromium is the
process of applying a protective coating on the surface of a metal
without using chromium. Such coatings are applied through phosphate
conversion (except for “Iron Phosphate Conversion Coating,” see
appendix B of this part), metal coloring, or passivation. Coatings
are applied to a base metal or previously deposited metal to
increase corrosion protection and lubricity, prepare the surface
for additional coatings, or formulate a special surface appearance.
This unit process includes sealant operations that use additives
other than chromium.
(1) In phosphate conversion, coatings are applied for one or
more of the following reasons: to provide a base for paints and
other organic coatings; to condition surfaces for cold forming
operations by providing a base for drawing compounds and
lubricants; to impart corrosion resistance to the metal surface; or
to provide a suitable base for corrosion-resistant oils or waxes.
Phosphate conversion coatings are formed by immersing a metal part
in a dilute solution of phosphoric acid, phosphate salts, and other
reagents.
(2) Metal coloring by chemical conversion coating produces a
large group of decorative finishes. Metal coloring includes the
formation of oxide conversion coatings. In this operation, the
metal surface is converted into an oxide or similar metallic
compound, giving the part the desired color. The most common
colored finishes are used on copper, steel, zinc, and cadmium.
(3) Passivation forms a protective coating on metals,
particularly stainless steel, by immersing the part in an acid
solution. Stainless steel is passivated to dissolve embedded iron
particles and to form a thin oxide film on the surface of the
metal. Wastewater generated during chemical conversion coating
includes spent solutions and rinses (i.e., both the chemical
conversion coating solutions and post-treatment sealant solutions).
These solutions commonly are discharged to a treatment system when
contaminated with the base metal or other impurities. Rinsing
normally follows each process step, except when a sealant dries on
the part surface.
Chemical Milling (or Chemical Machining) involves
removing metal from a part by controlled chemical attack, or
etching, to produce desired shapes and dimensions. In chemical
machining, a masking agent typically is applied to cover a portion
of the part's surface; the exposed (unmasked) surface is then
treated with the chemical machining solution. Wastewater generated
during chemical machining includes spent solutions and rinses.
Process solutions typically are discharged after becoming
contaminated with the base metal. Rinsing normally follows chemical
machining.
Chromate Conversion Coating (or Chromating) involves
forming a conversion coating (protective coating) on a metal by
immersing or spraying the metal with a hexavalent chromium compound
solution to produce a hexavalent or trivalent chromium compound
coating. This also is known as chromate treatment, and is most
often applied to aluminum, zinc, cadmium or magnesium surfaces.
Sealant operations using chromium also are included in this unit
operation. Chromate solutions include two types: (1) those that
deposit substantial chromate films on the substrate metal and are
complete treatments themselves, and (2) those that seal or
supplement oxide, phosphate, or other types of protective coatings.
Wastewater generated during chromate conversion coating includes
spent process solutions (i.e., both the chromate conversion
coating solutions and post-treatment sealant solutions) and rinses.
These solutions typically are discharged to a treatment system when
contaminated with the base metal or other impurities. Also,
chromium-based solutions, which are typically formulated with
hexavalent chromium, lose operating strength when the hexavalent
chromium reduces to trivalent chromium during use. Rinsing normally
follows each process step, except for sealants that dry on the
surface of the part.
Chromium Drag-out Destruction is a unit operation
performed following chromium-bearing operations to reduce
hexavalent chromium that is “dragged out” of the process bath.
Parts are dipped in a solution of a chromium-reducing chemical
(e.g., sodium metabisulfite) to prevent the hexavalent chromium
from contaminating subsequent process baths. This operation
typically is performed in a stagnant drag-out rinse tank that
contains concentrated chromium-bearing wastewater.
Cyanide Drag-out Destruction involves dipping part in a
cyanide oxidation solution (e.g., sodium hypochloride) to prevent
cyanide that is “dragged out” of a process bath from contaminating
subsequent process baths. This operation typically is performed in
a stagnant drag-out rinse tank.
Cyaniding Rinse is generated during cyaniding hardening
of a part. The part is heated in a molten salt solution containing
cyanide. Wastewater is generated when excess cyanide salt solution
is removed from the part in rinse water.
Electrochemical Machining is a process in which the part
becomes the anode and a shaped cathode is the cutting tool. By
pumping electrolyte between the electrodes and applying a current,
metal is rapidly but selectively dissolved from the part.
Wastewater generated during electrochemical machining includes
spent electrolytes and rinses.
Electroless Catalyst Solution involves adding a catalyst
just prior to an electroless plating operation to accelerate the
plating operation.
Electroless Plating involves applying a metallic coating
to a part using a chemical reduction process in the presence of a
catalysis. An electric current is not used in this operations. The
metal to be plated onto a part typically is held in solution at
high concentrations using a chelating agent. This plates all areas
of the part to a uniform thickness regardless of the configuration
of the part. Also, an electroless-plated surface is dense and
virtually nonporous. Copper and nickel electroless plating
operations are the most common. Sealant operations (i.e.,
other than hot water dips) following electroless plating are
considered separate unit operations if they include any additives.
Wastewater generated during electroless plating includes spent
process solutions and rinses. The wastewater contains chelated
metals, which require separate preliminary treatment to break the
metal chelates prior to conventional chemical precipitation.
Rinsing follows most electroless plating processes to remove
residual plating solution and prevent contamination of subsequent
process baths.
Electrolytic Cleaning involves removing soil, scale, or
surface oxides from a part by electrolysis. The part is one of the
electrodes and the electrolyte is usually alkaline. Electrolytic
alkaline cleaning and electrolytic acid cleaning are the two types
of electrolytic cleaning.
(1) Electrolytic alkaline cleaning produces a cleaner surface
than do nonelectrolytic methods of alkaline cleaning. This
operation uses strong agitation, gas evolution in the solution, and
oxidation-reduction reactions that occur during electrolysis. In
addition, dirt particles become electrically charged and are
repelled from the part surface.
(2) Electrolytic acid cleaning sometimes is used as a final
cleaning before electroplating. Sulfuric acid is most frequently
used as the electrolyte. As with electrolytic alkaline cleaning,
the mechanical scrubbing effect from the evolution of gas enhances
the effectiveness of the process.
Wastewater generated during electrolytic cleaning includes spent
process solutions and rinses. Electrolytic cleaning solutions
become contaminated during use due to the dissolution of the base
metal and the introduction of pollutants. The solutions typically
are batch discharged for treatment or disposal after they weaken.
Rinsing following electrolytic cleaning removes residual cleaner to
prevent contamination of subsequent process baths.
Electroplating with Chromium involves producing a
chromium metal coating on a surface by electrodeposition.
Electroplating provides corrosion protection, wear or erosion
resistance, lubricity, electrical conductivity, or decoration. In
electroplating, metal ions in acid, alkaline, or neutral solutions
are reduced on the cathodic surfaces of the parts being plated.
Metal salts or oxides typically are added to replenish the
solutions. Chromium trioxide often is added as a source of
chromium. In addition to water and the metal being deposited,
electroplating solutions often contain agents that form complexes
with the metal being deposited, stabilizers to prevent hydrolysis,
buffers for pH control, catalysts to assist in deposition, chemical
aids to dissolve anodes, and miscellaneous ingredients that modify
the process to attain specific properties. Sealant operations
performed after this operation are considered separate unit
operations if they include any additives (i.e., other than
hot water dips). Wastewater generated during electroplating
includes spent process solutions and rinses. Electroplating
solutions occasionally become contaminated during use due to the
base metal dissolving and the introduction of other pollutants,
diminishing the effectiveness of the electroplating solutions
diminishes. Spent concentrated solutions typically are treated to
remove pollutants and reused, processed in a wastewater treatment
system, or disposed of off site. Rinse waters, including some
drag-out rinse tank solutions, typically are treated on site.
Electroplating with Cyanide involves producing metal
coatings on a surface by electrodeposition using cyanide.
Electroplating provides corrosion protection, wear or erosion
resistance, electrical conductivity, or decoration. In
electroplating, metal ions in acid, alkaline, or neutral solutions
are reduced on the cathodic surfaces of the parts being plated. The
metal ions in solution typically are replenished by dissolving
metal from anodes contained in inert wire or metal baskets. Sealant
operations performed after this operation are considered separate
unit operations if they include any additives (i.e., any
sealant operations other than hot water dips). In addition to water
and the metal being deposited, electroplating solutions often
contain agents that form complexes with the metal being deposited,
stabilizers to prevent hydrolysis, buffers to control pH, catalysts
to assist in deposition, chemical aids to dissolve anodes, and
miscellaneous ingredients that modify the process to attain
specific properties. Cyanide, usually in the form of sodium or
potassium cyanide, frequently is used as a complexing agent for
zinc, cadmium, copper, and precious metal baths. Wastewater
generated during electroplating includes spent process solutions
and rinses. Electroplating solutions occasionally become
contaminated during use due to dissolution of the base metal and
the introduction of other pollutants, diminishing the performance
of the electroplating solutions. Spent concentrated solutions
typically are treated to remove pollutants and reused, processed in
a wastewater treatment system, or disposed of off site. Rinse
waters, including some drag-out rinse tank solutions, typically are
treated on site.
Electroplating without Chromium or Cyanide involves the
production of metal coatings on a surface by electrodeposition,
without using chromium or cyanide. Commonly electroplated metals
include nickel, copper, tin/lead, gold, and zinc. Electroplating
provides corrosion protection, wear or erosion resistance,
lubricity, electrical conductivity, or decoration. In
electroplating, metal ions in acid, alkaline, or neutral solutions
are reduced on the cathodic surfaces of the parts being plated. The
metal ions in solution typically are replenished by dissolving
metal from anodes contained in inert wire or metal baskets. Sealant
operations performed after this operation are considered separate
unit operations if they include any additives (i.e., any
sealant operations other than hot water dips). In addition to water
and the metal being deposited, electroplating solutions often
contain agents that form complexes with the metal being deposited,
stabilizers to prevent hydrolysis, buffers to control pH, catalysts
to assist in deposition, chemical aids to dissolve anodes, and
miscellaneous ingredients that modify the process to attain
specific properties. Wastewater generated during electroplating
without chromium or cyanide includes spent process solutions and
rinses. Electroplating solutions occasionally become contaminated
during use due to dissolution of the base metal and the
introduction of other pollutants, diminishing the effectiveness of
the electroplating solutions. Spent concentrated solutions
typically are treated for pollutant removal and reused, processed
in a wastewater treatment system, or disposed of off site. Rinse
waters, including some drag-out rinse tank solutions, typically are
treated on site.
Electropolishing involves producing a highly polished
surface on a part using reversed electrodeposition in which the
anode (part) releases some metal ions into the electrolyte to
reduce surface roughness. When current is applied, a polarized film
forms on the metal surface, through which metal ions diffuse. In
this operation, areas of surface roughness on parts serve as
high-current density areas and are dissolved at rates greater than
the rates for smoother portions of the metal surface. Metals are
electropolished to improve appearance, reflectivity, and corrosion
resistance. Base metals processed by electropolishing include
aluminum, copper, zinc, low-alloy steel, and stainless steel.
Common electrolytes include sodium hydroxide and combinations of
sulfuric acid, phosphoric acid, and chromic acid. Wastewater
generated during electropolishing includes spent process solutions
and rinses. Eventually, the concentration of dissolved metals
increases to the point where the process becomes ineffective.
Typically, a portion of the bath is decanted and either fresh
chemicals are added or the entire solution is discharged to
treatment and replaced with fresh chemicals. Rinsing can involve
several steps and can include hot immersion or spray rinses.
Galvanizing/Hot Dip Coating involves using various
processes to coat an iron or steel surface with zinc. In hot
dipping, a base metal is coated by dipping it into a tank that
contains a molten metal.
Hot Dip Coating involves applying a metal coating
(usually zinc) to the surface of a part by dipping the part in a
molten metal bath. Wastewater is generated in this operation when
residual metal coating solution is removed from the part in rinse
water.
Kerfing uses a tool to remove small amounts of metal from
a product surface. Water and synthetic coolants may be used to
lubricate the area between the tool and the metal, to maintain the
temperature of the cutting tool, and to remove metal fines from the
surface of the part. This operation generates oily wastewater that
contains metal fines and dust.
Laminating involves applying a material to a substrate
using heat and pressure.
Mechanical and Vapor Plating involves applying a metallic
coating to a part. For mechanical plating, the part is rotated in a
drum containing a water-based solution, glass beads, and metal
powder. In vapor plating, a metallic coating is applied by
atomizing the metal and applying an electric charge to the part,
which causes the atomized (vapor phase) metal to adhere to the
part. Wastewater generated in this operation includes spent
solutions from the process bath and rinse water. Typically, the
wastewater contains high concentrations of the applied metal.
Metallic Fiber Cloth Manufacturing involves weaving thin
metallic fibers to create a mesh cloth.
Metal Spraying (Including Water Curtain) involves
applying a metallic coating to a part by projecting molten or
semimolten metal particles onto a substrate. Coatings can be
sprayed from rod or wire stock or from powdered material. The
process involves feeding the material (e.g., wire) into a flame
where it is melted. The molten stock then is stripped from the end
of the wire and atomized by a high-velocity stream of compressed
air or other gas that propels the material onto a prepared
substrate or part. Metal spraying coatings are used in a wide range
of special applications, including: insulating layers in
applications such as induction heating coils; electromagnetic
interference shielding; thermal barriers for rocket engines;
nuclear moderators; films for hot isostatic pressing; and
dimensional restoration of worn parts. Metal spraying is sometimes
performed in front of a “water curtain” (a circulated water stream
used to trap overspray) or a dry filter exhaust hood that captures
the overspray and fumes. With water curtain systems, water is
recirculated from a sump or tank. Wastewater is generated when the
sump or tank is discharged periodically. Metal spraying typically
is not followed by rinsing.
Painting-Immersion (Including Electrophoretic, “E-coat”)
involves applying an organic coating to a part using processes such
autophoretic and electrophoretic painting.
(1) Autophoretic Painting involves applying an organic paint
film by electrophoresis when a part is immersed in a suitable
aqueous bath.
(2) Electrophoretic Painting is coating a part by making it
either anodic or cathodic in a bath that is generally an aqueous
emulsion of the organic coating material.
(3) Other Immersion Painting includes all other types of
immersion painting such as dip painting.
Water is used in immersion paint operations as a carrier for
paint particles and to rinse the part. Aqueous painting solutions
and rinses typically are treated through an ultrafiltration system.
The concentrate is returned to the painting solution, and the
permeate is reused as rinse water. Sites typically discharge a
bleed stream to treatment. The painting solution and rinses are
batch discharged periodically to treatment.
Photo Imaging is the process of exposing a
photoresist-laden printed wiring board to light to impact the
circuitry design to the board. Water is not used in this
operation.
Photo Image Developing is an operation in which a
water-based solution is used to develop the exposed circuitry in a
photoresist-laden printed wiring board. Wastewater generated in
this operation includes spent process solution and rinse water.
Photoresist Application is an operation that uses heat
and pressure to apply a photoresist coating to a printed wiring
board. Water is not used in this operation.
Photoresist Strip involves removing organic photoresist
material from a printed wiring board using an acid solution.
Phosphor Deposition is the application of a
phosphorescent coating to a part. Wastewater generated in this unit
operation includes water used to keep the parts clean and wet while
the coating is applied, and rinse water used to remove excess
phosphorescent coating from the part.
Physical Vapor Deposition involves physically removing a
material from a source through evaporation or sputtering, using the
energy of the vapor particles in a vacuum or partial vacuum to
transport the removed material, and condensing the removed material
as a film onto the surface of a part or other substrate.
Plasma Arc Machining involves removing material or
shaping a part by a high-velocity jet of high-temperature, ionized
gas. A gas (nitrogen, argon, or hydrogen) is passed through an
electric arc, causing the gas to become ionized, and heated to
temperatures exceeding 16,650 °C (30,000 °F). The relatively narrow
plasma jet melts and displaces the material in its path. Because
plasma arc machining does not depend on a chemical reaction between
the gas and the part, and because plasma temperatures are extremely
high, the process can be used on almost any metal, including those
that are resistant to oxygen-fuel gas cutting. The method is used
mainly for profile cutting of stainless steel and aluminum alloys.
Although plasma arc machining typically is a dry process, water is
used for water injection plasma arc torches. In these cases, a
constricted swirling flow of water surrounds the cutting arc. This
operations also may be performed immersed in a water bath. In both
cases, water is used to stabilize the arc, to cool the part, and to
contain smoke and fumes.
Plastic Wire Extrusion involves applying a plastic
material to a metal wire through an extrusion process.
Salt Bath Descaling involves removing surface oxides or
scale from a part by immersing the part in a molten salt bath or
hot salt solution. Salt bath descaling solutions can contain molten
salts, caustic soda, sodium hydride, and chemical additives. Molten
salt baths are used in a salt bath-water quench-acid dip sequence
to remove oxides from stainless steel and other corrosion-resistant
alloys. In this process, the part typically is immersed in the
molten salt, quenched with water, and then dipped in acid.
Oxidizing, reducing, or electrolytic salt baths can be used
depending on the oxide to be removed. Wastewater generated during
salt bath descaling includes spent process solutions, quenches, and
rinses.
Shot Tower - Lead Shot Manufacturing involves dropping
molten lead from a platform on the top of a tower through a
sieve-like device and into a vat of cold water.
Soldering involves joining metals by inserting a thin
(capillary thickness) layer of nonferrous filler metal into the
space between them. Bonding results from the intimate contact
produced by the metallic bond formed between the substrate metal
and the solder alloy. The term soldering is used where the melting
temperature of the filler is below 425 °C (800 °F). Some soldering
operations use a solder flux, which is an aqueous or nonaqueous
material used to dissolve, remove, or prevent the formation of
surface oxides on the part. Except for the use of aqueous fluxes,
soldering typically is a dry operation; however, a quench or rinse
sometimes follows soldering to cool the part or remove excess flux
or other foreign material from its surface. Recent developments in
soldering technology have focused on fluxless solders and fluxes
that can be cleaned off with water.
Solder Flux Cleaning involves removing residual solder
flux from a printed circuit board using either an alkaline or
alcohol cleaning solution.
Solder Fusing involves coating a tin-lead plated circuit
board with a solder flux and then passing the board through a hot
oil. The hot oil fuses the tin-lead to the board and creates a
solder-like finish on the board.
Solder Masking involves applying a resistive coating to
certain areas of a circuit board to protect the areas during
subsequent processing.
Sputtering is a vacuum evaporation process in which
portions of a coating material are physically removed from a
substrate and deposited a thin film onto a different substrate.
Stripping (Paint) involves removing a paint (or other
organic) coating from a metal basis material. Stripping commonly is
performed as part of the manufacturing process to recover parts
that have been improperly coated or as part of maintenance and
rebuilding to restore parts to a usable condition. Organic coatings
(including paint) are stripped using thermal, mechanical, and
chemical means. Thermal methods include burn-off ovens, fluidized
beds of sand, and molten salt baths. Mechanical methods include
scraping and abrasive blasting (as defined in “Abrasive Blasting”
in appendix B of this part). Chemical paint strippers include
alkali solutions, acid solutions, and solvents (e.g., methylene
chloride). Wastewater generated during organic coating stripping
includes process solutions (limited mostly to chemical paint
strippers and rinses).
Stripping (Metallic Coating) involves removing a metallic
coating from a metal basis material. Stripping is commonly part of
the manufacturing process to recover parts that have been
improperly coated or as part of maintenance and rebuilding to
restore parts to a usable condition. Metallic coating stripping
most often uses chemical baths, although mechanical means (e.g.,
grinding, abrasive blasting) also are used. Chemical stripping
frequently is performed as an aqueous electrolytic process.
Wastewater generated during metallic coating stripping includes
process solutions and rinses. Stripping solutions become
contaminated from dissolution of the base metal. Typically, the
entire solution is discharged to treatment. Rinsing is used to
remove the corrosive film remaining on the parts.
Thermal Infusion uses heat to infuse metal powder or dust
onto the surface of a part. Typically, thermal infusion is a dry
operation. In some cases, however, water may be used to remove
excess metal powder, metal dust, or molten metal.
Ultrasonic Machining involves forcing an abrasive liquid
between a vibrating tool and a part. Particles in the abrasive
liquid strike the part, removing any microscopic flakes on the
part.
Vacuum Impregnation is used to reduce the porosity of the
part. A filler material (usually organic) is applied to the surface
of the part and polymerized under pressure and heat. Wastewater is
generated in this unit operation when rinse water is used to remove
residual organic coating from the part.
Vacuum Plating involves applying a thin layer of metal
oxide onto a part using molten metal in a vacuum chamber.
Water Shedder involves applying a dilute water-based
chemical compound to a part to accelerate drying. This operation
typically is used to prevent a part from streaking when excess
water remains on the part.
Wet Air Pollution Control involves using water to remove
chemicals, fumes, or dusts that are entrained in air streams
exhausted from process tanks or production areas. Most frequently,
wet air pollution control devices are used with electroplating,
cleaning, and coating processes. A common type of wet air pollution
control is the wet packed scrubber consisting of a spray chamber
that is filled with packing material. Water is continuously sprayed
onto the packing and the air stream is pulled through the packing
by a fan. Pollutants in the air stream are absorbed by the water
droplets and the air is released to the atmosphere. A single
scrubber often serves numerous process tanks; however, the air
streams typically are segregated by source into chromium, cyanide,
and acid/alkaline sources. Wet air pollution control can be divided
into several suboperations, including:
(1) Wet Air Pollution Control for Acid Alkaline Baths;
(2) Wet Air Pollution Control for Cyanide Baths;
(3) Wet Air Pollution Control for Chromium-Bearing Baths;
and
(4) Wet Air Pollution Control for Fumes and Dusts.
Wire Galvanizing Flux involves using flux to remove rust
and oxide from the surface of steel wire prior to galvanizing. This
provides long-term corrosion protection for the steel wire.