Title 15

PART 745 APPENDIX



Supplement No. 1 to Part 745 - Schedules of Chemicals

15:2.1.3.4.30.0.1.3.50 :

Supplement No. 1 to Part 745 - Schedules of Chemicals
CAS
registry No.
Schedule 1
A. Toxic Chemicals:
1. Family: O-Alkyl(≤C10, incl. cycloalkyl) alkyl (Me, Et, n-Pr or i-Pr)- phosphonofluoridates
Not limited to the following examples:
Sarin: O-Isopropyl methylphosphonofluoridate 107-44-8
Soman: O-Pinacolyl methylphosphonofluoridate 96-64-0
2. Family: O-Alkyl (≤C10, incl. cycloalkyl) N,N-dialkyl (Me, Et, n-Pr or i-Pr) phosphoramidocyanidates
Not limited to the following example:
Tabun: O-Ethyl N,N-dimethyl phosphoramidocyanidate 77-81-6
3. Family: O-Alkyl (H or ≤C10, incl. cycloalkyl) S-2-dialkyl (Me, Et, n-Pr or i-Pr)-aminoethyl alkyl (Me, Et, n-Pr or i-Pr) phosphonothiolates and corresponding alkylated or protonated salts
Not limited to the following example:
VX: O-Ethyl S-2-diisopropylaminoethyl methyl phosphonothiolate 50782-69-9
4. Sulfur mustards:
2-Chloroethylchloromethylsulfide 2625-76-5
Mustard gas: Bis(2-chloroethyl)sulfide 505-60-2
Bis(2-chloroethylthio)methane 63869-13-6
Sesquimustard: 1,2-Bis(2-chloroethylthio)ethane 3563-36-8
1,3-Bis(2-chloroethylthio)-n-propane 63905-10-2
1,4-Bis(2-chloroethylthio)-n-butane 142868-93-7
1,5-Bis(2-chloroethylthio)-n-pentane 142868-94-8
Bis(2-chloroethylthiomethyl)ether 63918-90-1
O-Mustard: Bis(2-chloroethylthioethyl)ether 63918-89-8
5. Lewisites:
Lewisite 1: 2-Chlorovinyldichloroarsine 541-25-3
Lewisite 2: Bis(2-chlorovinyl)chloroarsine 40334-69-8
Lewisite 3: Tris(2-chlorovinyl)arsine 40334-70-1
6. Nitrogen mustards:
HN1: Bis(2-chloroethyl)ethylamine 538-07-8
HN2: Bis(2-chloroethyl)methylamine 51-75-2
HN3: Tris(2-chloroethyl)amine 555-77-1
7. Saxitoxin 35523-89-8
8. Ricin 9009-86-3
13. Family: P-alkyl (H or ≤C10, incl. cycloalkyl) N-(1-(dialkyl(≤C10, incl. cycloalkyl)amino))alkylidene(H or ≤C10, incl. cycloalkyl) phosphonamidic fluorides and corresponding alkylated or protonated salts
Not limited to the following examples:
N-(1-(di-n-decylamino)-n-decylidene)-P-decylphosphonamidic fluoride 2387495-99-8
Methyl-(1-(diethylamino)ethylidene)phosphonamidofluoridate 2387496-12-8
14. Family: O-alkyl (H or ≤C10, incl. cycloalkyl) N-(1-(dialkyl(≤C10, incl. cycloalkyl)amino))alkylidene(H or ≤C10, incl. cycloalkyl) phosphoramidofluoridates and corresponding alkylated or protonated salts
Not limited to the following examples:
O-n-Decyl N-(1-(di-n-decylamino)-n decylidene)phosphoramidofluoridate 2387496-00-4
Methyl (1-(diethylamino)ethylidene)phosphoramidofluoridate 2387496-04-8
Ethyl (1-(diethylamino)ethylidene)phosphoramidofluoridate 2387496-06-0
15. Methyl-(bis(diethylamino)methylene)phosphonamidofluoridate 2387496-14-0
16. Carbamates (quaternaries and bisquaternaries of dimethylcarbamoyloxypyridines)
16.1. Family: Quaternaries of dimethylcarbamoyloxypyridines: 1-[N,N-dialkyl(≤C10)-N-(n-(hydroxyl, cyano, acetoxy)alkyl(≤C10)) ammonio]-n-[N-(3-dimethylcarbamoxy-α-picolinyl)-N,N-dialkyl(≤C10) ammonio]decane dibromide (n=1-8)
Not limited to the following example:
1-[N,N-dimethyl-N-(2-hydroxy)ethylammonio]-10-[N-(3-dimethylcarbamoxy-α-picolinyl)-N,N-dimethylammonio]decane dibromide 77104-62-2
16.2. Family: Bisquaternaries of dimethylcarbamoyloxypyridines:1,n-Bis[N-(3-dimethylcarbamoxy-α-picolyl)-N,N-dialkyl(≤C10) ammonio]-alkane-(2,(n-1)-dione) dibromide (n=2-12)
Not limited to the following example:
1,10-Bis[N-(3-dimethylcarbamoxy-α-picolyl)-N-ethyl-N- methylammonio]decane-2,9-dione dibromide 77104-00-8
B. Precursors:
9. Family: Alkyl (Me, Et, n-Pr or i-Pr) phosphonyldifluorides
Not limited to the following example:
DF: Methylphosphonyldifluoride 676-99-3
10. Family: O-Alkyl (H or ≤C10, incl. cycloalkyl) O-2-dialkyl (Me, Et, n-Pr or i-Pr)-aminoethyl alkyl (Me, Et, n-Pr or i-Pr) phosphonites and corresponding alkylated or protonated salts
Not limited to the following example:
QL: O-Ethyl O-2-diisopropylaminoethyl methylphosphonite 57856-11-8
11. Chlorosarin: O-Isopropyl methylphosphonochloridate 1445-76-7
12. Chlorosoman: O-Pinacolyl methylphosphonochloridate 7040-57-5
Schedule 2
A. Toxic Chemicals:
1. Amiton: O,O-Diethyl S-[2-(diethylamino)ethyl] phosphorothiolate and corresponding alkylated or protonated salts 78-53-5
2. PFIB: 1,1,3,3,3-Pentafluoro-2-(trifluoromethyl)-1-propene 382-21-8
3. BZ: 3-Quinuclidinyl benzilate 6581-06-2
B. Precursors:
4. Family: Chemicals, except for those listed in Schedule 1, containing a phosphorus atom to which is bonded one methyl, ethyl or propyl (normal or iso) group but not further carbon atoms,
Not limited to the following examples:
Methylphosphonyl dichloride 676-97-1
Dimethyl methylphosphonate 756-79-6
Exemption: Fonofos: O-Ethyl S-phenyl ethylphosphonothiolothionate 944-22-9
5. Family: N,N-Dialkyl (Me, Et, n-Pr or i-Pr) phosphoramidic dihalides
6. Family: Dialkyl (Me, Et, n-Pr or i-Pr) N,N-dialkyl (Me, Et, n-Pr or i-Pr)-phosphoramidates
7. Arsenic trichloride 7784-34-1
8. 2,2-Diphenyl-2-hydroxyacetic acid 76-93-7
9. Quinuclidine-3-ol 1619-34-7
10. Family: N,N-Dialkyl (Me, Et, n-Pr or i-Pr) aminoethyl-2-chlorides and corresponding protonated salts
11. Family: N,N-Dialkyl (Me, Et, n-Pr or i-Pr) aminoethane-2-ols and corresponding protonated salts
Exemptions: N,N-Dimethylaminoethanol and corresponding protonated salts 108-01-0
N,N-Diethylaminoethanol and corresponding protonated salts 100-37-8
12. Family: N,N-Dialkyl (Me, Et, n-Pr or i-Pr) aminoethane-2-thiols and corresponding protonated salts
13. Thiodiglycol: Bis(2-hydroxyethyl)sulfide 111-48-8
14. Pinacolyl alcohol: 3,3-Dimethylbutane-2-ol 464-07-3
Schedule 3
A. Toxic Chemicals:
1. Phosgene: Carbonyl dichloride 75-44-5
2. Cyanogen chloride 506-77-4
3. Hydrogen cyanide 74-90-8
4. Chloropicrin: Trichloronitromethane 76-06-2
B. Precursors:
5. Phosphorus oxychloride 10025-87-3
6. Phosphorus trichloride 7719-12-2
7. Phosphorus pentachloride 10026-13-8
8. Trimethyl phosphite 121-45-9
9. Triethyl phosphite 122-52-1
10. Dimethyl phosphite 868-85-9
11. Diethyl phosphite 762-04-9
12. Sulfur monochloride 10025-67-9
13. Sulfur dichloride 10545-99-0
14. Thionyl chloride 7719-09-7
15. Ethyldiethanolamine 139-87-7
16. Methyldiethanolamine 105-59-9
17. Triethanolamine 102-71-6